绿色环保高效保温板研究

大部分常用的建筑外墙保温隔热材料原材料来源于化石资源。分析了常用保温材料对环境的影响,生产使用过程存在的环境污染问题,发展和提出了"声子共晶体"理论减少材料的热传递,从而构成绿色环保高效保温隔热板——"斯玛特"保温板(Smart Insulation,SIB),达到比常用保温隔热材料高的热阻,且所用原材料不来源于化石资源,生产使用过程绿色环保无污染。"斯玛特"保温板(SIB)是可持续发展的外墙保温材料,可替代目前常用的外墙保温隔热材料,使外墙保温隔热达到既节能又环保的可持续发展。     

聚合物水泥复合防水涂料的拉伸性能研究

本文就影响苯丙乳液-水泥复合防水涂料拉伸性能的诸多因素进行了系统的研究。试验结果表明,防水涂料的液粉比、灰聚比、养护制度,以及成膜助剂、增塑剂、水泥品种及其用量均对其涂膜的拉伸性能有显著的影响。     

填充油中多环芳烃含量的测定

建立采用核磁共振波谱法测定填充油中多环芳烃湾区氢(H_Bay)含量的方法。结果表明,在称样量为0.1 g、处理方式为样品经硅胶柱纯化后用氘代氯仿溶解的条件下,采用核磁共振波谱法进行测定,并按给定公式计算得到H_Bay含量,该方法的测试结果具有很好的重复性和再现性。     

氯碱化工“三废”零排放可行性研究

针对氯碱生产过程中产生大量的“工业三废”问题,介绍了焦煤集团开元化工有限责任公司的“三废”回收利用及治理情况,提出了实现“零排放工厂”的可行性方案和“三废”回收利用的治理措施。     

Study on aqueous film-forming foam extinguishing agent based on fluorocarbon cationic–hydrocarbon anionic surfactants mixture system

Fluorocarbon surfactants were the main components of aqueous film-forming foam extinguishing agents (AFFF). Unfortunately, the widely used fluorocarbon surfactant perfluorooctane sulfonate (PFOS) was limited due to its toxicity, bioaccumulation and biodegradability. In this paper, an environmentally friendly quaternary ammonium cationic fluorocarbon surfactant with high surface activity and simple synthesis route was reported. The surface performance and aggregation behavior of the mixed solution of this fluorocarbon surfactant and sodium n-octyl sulfate were studied by means of surface tension meter and transmission electron microscope (TEM). The results showed that the synergistic effect of sodium n-octyl sulfate and this fluorocarbon surfactant was significant, and many vesicles could be observed in the mixed solution with the concentration of 0.1 mol/L under TEM. Subsequently, three environmental friendly AFFF formulations (F-1, F-2, F-3) were designed with the mixture of the fluorocarbon surfactant, sodium n-octyl sulfate and lauryl betaine BS-12 as foaming agent. Through its foam performance test, it could be seen that F-3 showed relatively excellent foam performance. The initial foam height h₀ was 70 mm, the 25% drainage time was 315 s, the extinguishing time was 28 s, and the burn-back time was 720 s. This kind of fire extinguishing agent had the potential of fire protection application.     

生态环境友好型混凝土的研究现状与展望

分析探讨了混凝土对环境造成的危害，为实现可持续发展，必须开展生态环境友好型混凝土的研究。介绍了三类生态环境友好型混凝土的组成、结构和性能，提出了这种混凝土新材料今后的研究方向，是将粉煤灰等工业废渣的治理与生态环境治理和保护结合起来。     

城市公共空间环境设计中的生态原则

选择对城市建设有深远影响的城市公共空间环境作为研究对象,以生态学视角为研究的突破口,架构与生态相适应的设计原则,旨在营建与自然和谐的、舒适宜人的特色城市环境。     

XGNA-12环保型充气柜技术参数的计算

在新产品的设计过程中,为了使产品的各个方面能够顺利的达到预期的目标,需要对多项技术参数进行计算,并要求其满足特定的要求。针对XGNA-12环保型充气柜产品的结构特点,对接触电阻、密封箱体气体压力和水分含量、触头压力等几种技术参数进行计算,为产品的开发和完善提供了理论基础。     

Assessing the Antimicrobial Activity of Polyisoprene Based Surfaces

There has been an intense research effort in the last decades in the field of biofouling prevention as it concerns many aspects of everyday life and causes problems to devices, the environment, and human health. Many different antifouling and antimicrobial materials have been developed to struggle against bacteria and other micro- and macro-organism attachment to different surfaces. However the “miracle solution” has still to be found. The research presented here concerns the synthesis of bio-based polymeric materials and the biological tests that showed their antifouling and, at the same time, antibacterial activity. The raw material used for the coating synthesis was natural rubber. The polyisoprene chains were fragmented to obtain oligomers, which had reactive chemical groups at their chain ends, therefore they could be modified to insert polymerizable and biocidal groups. Films were obtained by radical photopolymerization of the natural rubber derived oligomers and their structure was altered, in order to understand the mechanism of attachment inhibition and to increase the efficiency of the anti-biofouling action. The adhesion of three species of pathogenic bacteria and six strains of marine bacteria was studied. The coatings were able to inhibit bacterial attachment by contact, as it was verified that no detectable leaching of toxic molecules occurred.     

高硅钢用半有机绝缘涂层的制备及其性能研究

为减少高硅钢铁芯叠片间的涡流损耗,以磷酸二氢铝、苯丙乳液、甘油及水为主要原料,制备出一种适合高硅钢用无铬环保半有机绝缘涂层.利用光电子谱仪、扫描电镜及能谱仪对高硅钢脱碳退火板的氧化薄膜、绝缘涂层的微观结构形貌及部分缺陷进行分析,并研究了该涂层的涂覆量对其附着性、硬度及绝缘性能的影响.研究结果表明:普通无取向硅钢磷酸盐环保半有机绝缘涂层同样适用于高硅钢;绝缘涂层的均匀性取决于高硅钢片表面的平整度、涂辊表面质量以及对涂覆速度的平稳控制;高硅钢的表面粗糙度及氧化膜厚度对绝缘涂层的附着性有着重要影响;本试验制备的半有机涂层每面涂覆量控制在0.8~1.2 g/m2,具有良好的附着性及绝缘性能,层间电阻在5Ω·cm2/片以上.